Metal carbonyls supported on iron oxide nanoparticles to trigger the CO-gasotransmitter release by magnetic heating.

نویسندگان

  • Peter C Kunz
  • Hajo Meyer
  • Juri Barthel
  • Silvio Sollazzo
  • Annette M Schmidt
  • Christoph Janiak
چکیده

Magnetic iron oxide, maghemite (Fe2O3) nanoparticles with covalent surface-bound CO-releasing molecules (CORMs) can be triggered to release CO through heating in an alternating magnetic field. In the proof-of-concept study the rate of CO-release from [RuCl(CO3)(μ-DOPA)]@maghemite nanoparticles was doubled upon exposure to an external alternating magnetic field (31.7 kAm(-1), 247 kHz, 25 °C, 39.9 mTesla, DOPA = dioxyphenyl-alaninato).

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عنوان ژورنال:
  • Chemical communications

دوره 49 43  شماره 

صفحات  -

تاریخ انتشار 2013